reports that a mouse study published in the Journal of Medicinal Food found that milk taken from cows during the night had greater sedative effects than milk collected during the day. The reason suggested is that milk collected at night had 24% more tryptophan and about ten times as much melatonin as milk collected during the day.
http://www.wsj.com/articles/got-night-milk-a-possible-treatment-for-anxiety-insomnia-1449503741
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